Skip to main content
Product: 22560-16-3 Lithium Triethylborohydride

Lithium Triethylborohydride, typ. 12 % solution in THF (typ. 1.0 M)

C6-H16-B .Li

CAS Number: 22560-16-3
EC Number: 245-076-8
Material REACH Number: 01-2120763165-54-0000

Lithium Triethylborohydride (CAS 22560-16-3) is a metal hydride reducing agent with molecular formula C6-H16-B .Li. It is supplied as a typical 12% solution in THF.

It is primarily used as a reducing agent in organic synthesis. Powerful and selective reducing agent for several functional groups like ester or amides.

Many reagents in this class react readily with moisture and oxygen. Handle under dry, inert conditions using air‐ and water‐free techniques, and add slowly/with cooling when quenching or charging to control heat release. Consult the SDS and site-specific procedures for compatible materials, fire response, and storage.

Physical and Chemical Properties
Property Value
IUPAC Name
 
Molecular Weight
105.94g/mol
Appearance
Liquid
Color
Colorless
Flash Point
-21.2 °C 1,013 hPa (Tetrahydrofuran)
Boiling Point
65 °C at 1,013 hPa (Tetrahydrofuran)
Density
0.89 g/cm3 at 20 °C
Solubility in Water
(Not applicable)

Applications

Powerful and selective reducing agent for several functional groups like ester or amides

Specifications

  • Lithium Triethylborohydride: 11 - 13 %

    Method of Analysis

    Volumetric determination of hydrogen gas evolved on hydrolysis. Detailed description available on request.

    Handling and Storage

    Handling Instructions

    The material should only be handled under inert gas. Contact with air and moisture results in rapid decomposition. Vapors may form explosive mixtures with air. Vapors are heavier than air and may spread along floors. Flash back possible over considerable distance. Use only explosion-proof equipment. Protect from heat and direct sunlight. Never add water or oxidizing materials. Do not store near acids. In case of fire use dry extinguishers on basis of sodium chloride or limestone powder. Never use water, CO2 or foam. Pay attention to the Safety Data Sheet - Section 7.

    Storage Instructions

    When stored according to MSDS the material has limited stability due to decomposition over time. We therefore recommend to consume the material within a period of 6 months after receipt. For optimum storage stability keep temperatures between -10°C and 5°C.